2021

Arlt, S., Blaesing, K., Harloff, J., Laatz, K.C., Michalik, D., Nier, S., Schulz, A., Stoer, P., Stoffers, A., Villinger, A. (2021): Pseudohalogen Chemistry in Ionic Liquids with Non-innocent Cations and Anions. ChemistryOpen 10: 62-71, DOI: 10.1002/open.202000252

Bresien, J., Michalik, D., Schulz, A., Villinger, A., Zander, E. (2021): Azadiphosphaindane-1,3-diyls: A Class of Resonance-Stabilized Biradicals. Angewandte Chemie Internationale Edition 60 [3]: 1507-1512, DOI: 10.1002/anie.202011886

Fischer, M., Hering-Junghans, C. (2021): On 1,3-phosphaazaallenes and their diverse reactivity. Chem. Sci. 12, 10279. Chemical Science 12: 10279–1028, DOI: 10.1039/d1sc02947a

Schulz, A., Hinz, A., Roelke, A., Villinger, A., Wustrack, R. (2021): On New Staudinger Type Reactions of Phosphorus Centered Biradicaloids, [P(μ-NR)]2 (R = Ter, Hyp), with Ionic and Covalent Azides. Zeitschrift für anorganische und allgemeine Chemie 647 [4]: 245-257, DOI: 10.1002/zaac.202000228

2020

Beer, H., Bläsing, K., Bresien, J., Chojetzki, L., Schulz, A., Stoer, P., Villinger, A. (2020): Trapping of Bronsted acids with a phosphorus-centered biradicaloid - synthesis of hydrogen pseudohalide addition products. Dalton Transactions - The international journal for inorganic, organometallic and bioinorganic chemistry 49: 13655-1366, DOI: 10.1039/d0dt03251d

Beer, H., Bresien, J., Michalik, D., Rölke, A.-K., Schulz, A., Villinger, A., Wustrack, R. (2020): Heterocyclopentanediyls vs Heterocyclopentadienes: A Question of Silyl Group Migration. Journal of Organic Chemistry 85: 14435-1444, DOI: 10.1021/acs.joc.0c00460

Beer, H., Bresien, J., Michalik, D., Schulz, A., Villinger, A. (2020): Reversible switching between housane and cyclopentanediyl isomers: an isonitrile-catalyzed thermal reverse reaction. Dalton Transactions - The international journal for inorganic, organometallic and bioinorganic chemistry 49: 13986-1399, DOI: 10.1039/D0DT02688C

Bresien, J., Pilopp, Y., Schulz, A., Szych, L.S., Villinger, A., Wustrack, R. (2020): Synthesis of Sterically Demanding Secondary Phosphides and Diphosphanes and Their Utilization in Small-Molecule Activation. Inorganic Chemistry 59: 13561-1357, DOI: 10.1021/acs.inorgchem.0c01934

Chojetzki, L., Schulz, A., Villinger, A., Wustrack, R. (2020): Cycloaddition of Alkenes and Alkynes to the P-centered Singlet Biradical [P(μ-NTer)]2. Zeitschrift für anorganische und allgemeine Chemie 646: 614-624, DOI: 10.1002/zaac.201900191

Grandane, A., Nocentini, A., Werner, T., Zalubovskis, R., Supuran, C.T. (2020): Benzoxepinones: A new isoform-selective class of tumor associated carbonic anhydrase inhibitors. Bioorganic & Medicinal Chemistry 28 [11]: 115496, DOI: 10.1016/j.bmc.2020.115496

Harloff, J., Schulz, A., Stoer, P., Villinger, A. (2020): Pseudohalide HCN aggregate ions: [N3(HCN)3]-, [OCN(HCN)3]-, [SCN(HCN)2]- and [P(CN·HCN)2]-. Dalton Transactions - The international journal for inorganic, organometallic and bioinorganic chemistry 49: 13345-1335, DOI: 10.1039/d0dt02973d

Hu, Y., Peglow, S., Longwitz, L., Frank, M., Epping, J.D., Brüser, V., Werner, T. (2020): Plasma‐Assisted Immobilization of a Phosphonium Salt and Its Use as a Catalyst in the Valorization of CO2. ChemSusChem 13: 1825 –1833, DOI: 10.1002/cssc.201903384

Hu, Y., Wei, Z., Frey, A., Kubis, C., Ren, C.-Y., Spannenberg, A., Jiao, H., Werner, T. (2020): Catalytic, kinetic and mechanistic insights into the fixation of CO2 with epoxides catalyzed by phenol functionalized phosphonium salts. ChemSusChem, DOI: 10.1002/cssc.202002267

Hülsewede, D., Temmel, E., Kumm, P., von Langermann, J. (2020): Concept Study for an Integrated Reactor-Crystallizer Process for the Continuous Biocatalytic Synthesis of (S)-1-(3-Methoxyphenyl)ethylamine. Crystals 10 [15]: 1-13, DOI: 10.3390/cryst10050345

Liu, X., Longwitz, L., Spiegelberg, B., Tönjes, J., Beweries, T., Werner, T. (2020): Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions. ACS Catalysis 2020 [10]: 13659–1366, DOI: 10.1021/acscatal.0c03294

Meyer, L.-E., Brundiek, H., von Langermann, J. (2020): Integration of ion exchange resin materials for a downstream-processing approach of an imine reductase-catalyzed reaction. Biotechnology Progress 36 [5]:, DOI: 10.1002/btpr.3024

2019

Büttner, H., Kohrt, C., Wulf, C., Schäffner, B., Groenke, K., Hu, Y., Kruse, D., Werner, T. (2019): Life Cycle Assessment for the Organocatalytic Synthesis of Glycerol Carbonate Methacrylate. ChemSusChem 12: 2701-2707, DOI: 10.1002/cssc.201900678

Grandane, A., Longwitz, L., Roolf, C., Spannenberg, A., Murua Escobar, H., Junghans, C., Suna, E., Werner, T. (2019): Intramolecular Base-Free Catalytic Wittig Reaction: Synthesis of Benzoxepinones. Journal of Organic Chemistry 84: 1320-1329.

Hülsewede, D., Meyer, L.-E., von Langermann, J. (2019): Application of in situ-Product Crystallization and Related Techniques in Biocatalytic Processes. Chemistry - A European Journal 25: 4871-4884, DOI: 10.1002/chem.201804970

Jahanbakhsh, S., Brüser, V., Brandenburg, R. (2019): Experimental investigation of single microdischarges in a barrier corona arrangement with a cathodic metal pin. Plasma Sources Science and Technology, DOI: 10.1088/1361-6595/ab52e9

Liu, X., de Vries, J. G., Werner, T. (2019): Transfer Hydrogenation of Cyclic Carbonates and Polycarbonate to Methanol and Diols by Iron Pincer Catalysts. Green Chemistry 21: 5248-5255, DOI: 10.1039/C9GC02052G

Longwitz, L., Jopp, S., Werner, T. (2019): Organocatalytic Chlorination of Alcohols by P(III)/P(V) Redox Cycling. Journal of Organic Chemistry 84: 7863–7870, DOI: 10.1021/acs.joc.9b00741

Longwitz, L., Spannenberg, A., Werner, T. (2019): Phosphetane Oxides as Redox Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature. ACS Catalysis, DOI: 10.1021/acscatal.9b02456

Longwitz, L., Werner, T. (2019): Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling. Pure and Applied Chemistry 91 [1]: 95-102, DOI: 10.1515/pac-2018-0920

Longwitz, L., Werner, T. (2019): The Mitsunobu reaction, reimagined. Science 365: 866-867, DOI: 10.1126/science.aay6635

Longwitz, L., Werner, T. (2019): Reduction of activated alkenes by P(III)/P(V) redox cycling catalysis. Angewandte Chemie Internationale Edition, DOI: 10.1002/anie.201912991

Meyer, L.‐E., Gummesson, A., Kragl, U., von Langermann, J. (2019): Application of Ionic Liquid-Water-Based Thermomorphic Solvent (TMS)-Systems for Biocatalytic Reactions. Biotechnology Journal, DOI: 10.1002/biot.201900215

2018

Felgenhauer, P., Labbow, R., Schulz, A., Villinger, A. (2018): Synthesis and Characterization of Silylated Phosphonium [P(OSiMe3)4]+ and Phosphate [O2P(OSiMe3)2]− Salts. Inorganic Chemistry 57 (15: 9348–9353, DOI: 10.1021/acs.inorgchem.8b01323

Longwitz, L., Steinbauer, J., Spannenberg, A., Werner, T. (2018): Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions. ACS Catalysis 8: 665-672, DOI: 10.1021/acscatal.7b03367

Schulz, A., Bresien, J., Hinz, A., Villinger, A. (2018): As-N and As-N-P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls. Eur. J. Inorg. Chem. 10.1002/ejic.201800109, DOI: 10.1002/ejic.201800109

2017

Boeck, G., Peppel, T., Selent, D., Schulz, A. (2017): Chemie in Rostock heute. Nachrichten aus der Chemie 65 [10]: 1030-1033, DOI: 10.1002/nadc.20174062644

Büttner, H.; Steinbauer, J.; Wulf, C.; Dindaroglu, M.; Schmalz, H.-G.; Werner, T. (2017): Organocatalyzed Synthesis of Oleochemical Carbonates from CO2 and Renewables. ChemSusChem 10 [6]: 1076-1079, DOI: 10.1002/cssc.201601163

Hinz, A., Labbow, R., Rennick, C., Schulz, A., Goicoechea, J.M. (2017): HPCO—A Phosphorus-Containing Analogue of Isocyanic Acid. Angewandte Chemie Internationale Edition 56 [14]: 3911-3915, DOI: 10.1002/anie.201700368

Hoehne, M., Joksch, M., Konieczny, K., Mueller, B.H., Spannenberg, A., Peulecke, N., Rosenthal, U. (2017): Selective Reductions of N,N-Bis{chloro(aryl)- phosphino}-amines Yielding Three-, Five-, Six-, and Eight-Membered Cyclic Azaphosphanes. Chemistry - A European Journal 23 [18]: 4298-4309, DOI: 10.1002/chem.201605836

Müller, B.H., Konieczny, K., Höhne, M., Spannenberg, A., Peulecke, N., Moritz, J.O., Winterberg, M., Rosenthal, U. (2017): Synthesis of 1,2,4-triaza-3,5-diphospholidines. Monatshefte für Chemie - Chemical Monthly 1-7, DOI: 10.1007/s00706-017-2082-x

Rosenthal, U., Höhne, M., Müller, B.H., Peulecke, N., Spannenberg, A., Jiao, H. (2017): Highly Selective Chromium(0) Mediated Insertion of Nitriles into a Non-polar P-P Bond of a Substituted Hexahydro-1,4-Diaza-2,3,5,6-Tetraphosphorine. European Journal of Inorganic Chemistry, DOI: 10.1002/ejic.201700634

Schulz, A., Bresien, J., Hinz, A., Suhrbier, T., Thomas, M., Villinger, A. (2017): Dichloro-cycloazatriphosphane — the missing link between N2P2 and P4 ring systems in the systematic development of NP chemistry. Chemistry - A European Journal 23 [59]: 14738–1474, DOI: 10.1002/chem.201704278

Steinbauer, J., Longwitz, L., Frank, M., Epping, J., Kragl, U., Werner, T. (2017): Immobilized bifunctional phosphonium salts as recyclable organocatalysts in the cycloaddition of CO2 and epoxides. Green Chemistry 19: 4435-4445, DOI: 10.1039/C7GC01782K

Steinbauer, J., Werner, T. (2017): Poly(ethylene glycol)s as Ligands in Calcium-Catalyzed Cyclic Carbonate Synthesis. ChemSusChem 10 [15]: 3025-3029, DOI: 10.1002/cssc.201700788

2016

Adam, R., Alberico, E., Baumann, W., Drexler, H.-J., Jackstell, R., Junge, H., Beller, M. (2016): NNP-type pincer imidazolylphosphine ruthenium complexes: Efficient Base-Free Hydrogenation of Aromatic and Aliphatic Nitriles under Mild Conditions. Chemistry - A European Journal 22: 4991-5002, DOI: 10.1002/chem.201504709

Adam, R., Bheeter, C.B., Jackstell, R., Beller, M. (2016): A Mild and Base-Free Protocol for the Ruthenium- Catalyzed Hydrogenation of Aliphatic and Aromatic Nitriles with Tridentate Phosphine Ligands. ChemCatChem 8: 1329-1334, DOI: 10.1002/cctc.201501367

Bläsing, K., Ellinger, S., Harloff, J., Schulz, A., Sievert, K., Täschler, C., Villinger, A., Zur Täschler, C. (2016): Lewis Acid Catalyzed Synthesis of Cyanidophosphates. Chemistry - A European Journal 22 [12]: 4175–4188, DOI: 10.1002/chem.201504523

Bresien, J., Faust, K., Hering-Junghans, C., Rothe, J., Schulz, A., Villinger A. (2016): Synthetic strategies to bicyclic tetraphosphanes using P1, P2 and P4 building blocks. Dalton Transactions - The international journal for inorganic, organometallic and bioinorganic chemistry 05/2016:, DOI: 10.1039/C5DT02757H

Büttner, H., Grimmer, C., Steinbauer, J., Werner, T. (2016): Iron-based binary catalytic system for the valorization of CO2 into bio-based cyclic carbonates. ACS Sustainable Chemistry and Engineering 4 [9]: 4805-4814.

Hinz, A., Kuzora, R., Rölke, A.-K., Schulz, A., Villinger, A., Wustrack, R. (2016): Synthesis of a Silylated Phosphorus Biradicaloid and Its Utilization in the Activation of Small Molecules. European Journal of Inorganic Chemistry, DOI: 10.1002/ejic.201600321

Hinz, A., Rothe, J., Schulz, A., Villinger, A. (2016): Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication. Dalton Transactions - The international journal for inorganic, organometallic and bioinorganic chemistry 45: 6044-6052, DOI: 10.1039/C5DT02711J

Hinz, A., Schulz, A., Villinger, A. (2016): Synthesis of Heavy Cyclodipnictadiphosphanes [ClE(μ-P-Ter)]2 [E = P, As, Sb, or Bi; Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl]. Inorganic Chemistry 55: 3692–3699, DOI: 0.1021/acs.inorgchem.6b00218

Jungk, P., Täufer, T., Thiel, I., Hapke, M. (2016): Synthesis of Chiral Indenylcobalt(I) Complexes and Their Evaluation in Asymmetric [2+2+2] Cycloaddition Reactions. Synthesis 48 [13]: 2026-2035, DOI: 10.1055/s-0035-1560433

Leibniz ScienceCampus Phosphorus Research Rostock (2016): Phosphorus 2020 - Challenges for Synthesis, Agriculture and Ecosystems. Conference Proceedings of the 8th International Phosphorus Workshop (IPW8), 12.-16.09.2016, Rostock, DOI: 10.12754/procs-2016-i

Pews-Davtyan, A., Jackstell, R., Spannenberg, A., Beller, M. (2016): Zwitterionic phosphonium ligands: synthesis, characterization and application in telomerization of 1,3-butadiene. Chemical Communications 52: 7568-7571, DOI: 10.1039/C6CC02747D

Rodrigues, C., Delolo, F.G., Ferreira, L. M., da S. Maia, P.I., Deflon, V.M., Rabeah, J,, Brückner, A., Norinder, J., Börner, A., Bogado, A.L.; Batista, A.A. (2016): Ruthenium(III)/phosphine/pyridine complexes applied in the hydrogenation reactions of polar and apolar double bonds. Journal of molecular structure 1111: 84-89.

Schirmer, M.-L., Adomeit S., Spannenberg, A., Werner, T. (2016): Novel Base-Free Catalytic Wittig Reaction for the Synthesis of Highly Functionalized Alkenes. Chemistry - A European Journal 22: 2458-2465.

Schirmer, M.-L., Jopp, S., Holz, J., Spannenberg, A., Werner, T. (2016): Organocatalyzed Reduction of Tertiary Phosphine Oxides. Advanced Synthesis & Catalysis 358: 26-29.

Schirmer, M.-L., Spannenberg, A., Werner, T. (2016): Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (E)-3-benzyl-idenepyrrolidine-2,5-dione, (E)-3-benzyl-idene-1-methyl-pyrrolidine-2,5-dione and (E)-3-benzyl-idene-1-tert-but-ylpyrrolidine-2,5-. Acta Cryst C72: 504-508, DOI: 10.1107/S2053229616008159

Tenhumberg, N., Büttner, H., Schäffner, B., Kruse, D., Blumenstein, M., Werner, T. (2016): Cooperative Catalyst System for the Synthesis of Oleochemical Cyclic Carbonates from CO2 and Renewables. Green Chemistry, DOI: 10.1039/C6GC00671J

2015

Bresien, J., Faust, K., Schulz, A., Villinger, A. (2015): Low-Temperature Isolation of the Bicyclic Phosphinophosphonium Salt [Mes*2P4Cl][GaCl4]. Angewandte Chemie Internationale Edition 54: 6926 – 693.

Bresien, J., Schulz, A., Villinger, A. (2015): A Tricyclic Hexaphosphane. Chemistry - A European Journal 21 [51]: 18543-1854, DOI: 10.1002/chem.201503808

Brückner, A., Hinz, A., Priebe, J. B., Schulz, A., Villinger, A. (2015): Cyclic Group 15 Radical Cations. Angewandte Chemie Internationale Edition 54 [25]: 7426–7430, DOI: 10.1002/anie.201502054

Büttner, H., Steinbauer, J.,Werner, T. (2015): Synthesis of cyclic carbonates from epoxides and CO2 using bifunctional one-component phosphorus-based organocatalysts. ChemSusChem 8: 2655–2669, DOI: 10.1002/cssc.201500612

Großeheilmann,J., Büttner, H., Kohrt, C., Kragl, U., Werner, T. (2015): Recycling of phosphorus-based organocatalysts by organic solvent nanofiltration. ACS Sustainable Chemistry and Engineering 3: 2817–2822, DOI: 10.1021/acssuschemeng.5b00734

Haerzschel, S., Kuehn, F., Woehl, A., Mueller, W., Al-Hazmi, M.H., Alqahtani, A.M., Mueller, B.H., Peulecke, N., Rosenthal, U. (2015): Comparative study of new chromium-based catalysts for the selective tri- and tetramerization of ethylene. Catalysis Science & Technology 5: 1678-1682, DOI: 10.1039/C4CY01441C

Hinz, A., Schulz, A., Villinger, A. (2015): A Mixed Arsenic–Phosphorus Centered Biradicaloid. Angewandte Chemie Internationale Edition 54: 668-672, DOI: 10.1002/anie.201408639

Hinz, A., Schulz, A., Villinger, A. (2015): P–P sigma-bond activation by gold(I) coordination. Chemical Communications 51: 1363-1366, DOI: 10.1039/C4CC09164G

Hoffmann, M., Deshmukh, S., Werner, T. (2015): Scope and Limitation of the Microwave-Assisted Catalytic Wittig Reaction. European Journal of Organic Chemistry 4532-4543.

Schirmer, M.-L., Adomeit, S., Werner, T. (2015): First Base-Free Catalytic Wittig Reaction. Organic Letters 17: 3078-3081.

Schirmer, M.-L., Spannenberg, A., Werner, T. (2015): Crystal structure of diethyl (E)-2-[(benzo­furan-2-yl)methyl­idene]succinate. Acta Cryst E71: 0872.

Werner, T., Hoffmann, M., Deshmukh, S. (2015): Phospholane catalyzed Wittig reaction. European Journal of Organic Chemistry 3286-3295.

2014

Banerjee, D., Junge, K., Beller, M. (2014): Cooperative catalysis by palladium and a chiral phosphoric acid: enantioselective amination of racemic allylic alcohols. Angewandte Chemie Internationale Edition 53: 13049-1305, DOI: 10.1002/anie.201405511

Heinig, S., Wöhl, A., Müller, W., Al-Hazmi, M.H., Müller, B.H., Peulecke, M., Rosenthal, U. (2014): Influence of Ph2PN(R)P(Ph)N(R)H (R=c-Hex, iPr) Ligand Substituents, Modifier, and Process Parameters on Reaction Kinetics of a Chromium-based Catalyst for the Selective Trimerization of Ethylene. ChemCatChem 6 [2]: 514–521, DOI: 10.1002/cctc.201300652

Hinz, A., Kuzora, R., Rosenthal, U., Schulz, A., Villinger, A. (2014): Activation of small molecules by phosphorus biradicaloids. Chemistry - A European Journal 20: 14659–1467, DOI: 10.1002/chem.201403964

Werner, T., Büttner, H. (2014): Phosphorous based bifunctional organocatalysts for the addition of CO2 and epoxides. ChemSusChem 7(12&#: 3268-3271, DOI: 10.1002/cssc.201402477R1

Werner, T., Hoffmann, M. (2014): First Enantioselective Catalytic Wittig Reaction. European Journal of Organic Chemistry 2014 (: 6630-6633, DOI: 10.1002/ejoc.201402941

Werner, T., Hoffmann, M., Deshmukh, S. (2014): First Microwave Assisted Catalytic Wittig Reaction. 2014 (: 6873-6876, DOI: 10.1002/ejoc.201403113

2011

Werner, T., Riahi, A.M., Schramm, H. (2011): Phosphonium Salt Catalyzed Addition of Diethylzinc to Aldehydes. Synthesis 2011: 3482-3490.